Zinc nitrate

Synthesis

Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid: : : These reactions are accompanied by the hydration of the zinc nitrate.

The anhydrous salt arises by the reaction of anhydrous zinc chloride with nitrogen dioxide: :

Reactions

Treatment of zinc nitrate with acetic anhydride gives zinc acetate.

On heating, zinc nitrate undergoes thermal decomposition to form zinc oxide, nitrogen dioxide and oxygen: :

Aqueous zinc nitrate contains aquo complexes . and, thus, this reaction may be better written as the reaction of the aquated ion with hydroxide through donation of a proton, as follows.

Applications

Zinc nitrate has no large scale application but is used on a laboratory scale for the synthesis of coordination polymers. Its controlled decomposition to zinc oxide has also been used for the generation of various ZnO based structures, including nanowires.

It is used as a corrosion inhibitor.

It can be used as a mordant in dyeing. An example reaction gives a precipitate of zinc carbonate: :

References

References

1. {{Greenwood&Earnshaw2nd
2. (1963). "Handbook of Preparative Inorganic Chemistry, 2nd Ed.". Academic Press.
3. Sze, Yu-Keung, and Donald E. Irish. "Vibrational spectral studies of ion-ion and ion-solvent interactions. I. Zinc nitrate in water." ''[[Journal of Solution Chemistry]]'' 7.6 (1978): 395-415.
4. (November 2003). "Structural diversity of building-blocks in coordination framework synthesis—combining M(NO3)2 junctions and bipyridyl ligands". Coordination Chemistry Reviews.
5. (September 2006). "Solution-Grown Zinc Oxide Nanowires". Inorganic Chemistry.
6. (10 March 2025). "Zinc nitrate uses". Amizara Speciality Chemicals LLP.