Tetryl

Chemical properties

Tetryl is a yellow crystalline solid powder material, practically insoluble in water but soluble in acetone, benzene and other solvents. When tetryl is heated, it first melts, then decomposes and explodes. It burns readily and is more easily detonated than ammonium picrate or TNT, being about as sensitive as picric acid. It is detonated by friction, shock, or spark. It remains stable at all temperatures which may be encountered in storage. It is generally used in the form of pressed pellets, and has been approved as the standard bursting charge for small-caliber projectiles, since it gives much better fragmentation than TNT. It has an explosive velocity of 23,600 –. Tetryl is the basis for the service tetryl blasting caps necessary for positive detonation of TNT. A mixture of mercury fulminate and potassium chlorate is included in the cap to ensure detonation of tetryl.

Environmental effect

The most toxic ordnance compounds‌tetryl and 1,3,5-trinitrobenzene‌are also the most degradable. Therefore, these chemicals are expected to be short-lived in nature, and environmental impacts would not be expected in areas that are not currently subject to chronic inputs of these chemicals. Tetryl decomposes rapidly in methanol/water solutions, as well as with heat. All aqueous samples expected to contain tetryl should be diluted with acetonitrile prior to filtration and acidified to {{nowrap|pH

History and synthesis

Tetryl was used mainly during World Wars I and II and later conflicts. Tetryl is usually used on its own, though can sometimes be found in compositions such as tetrytol. Tetryl is no longer manufactured or used in the United States, but can still be found in legacy munitions such as the M14 anti-personnel landmine.

Dutch chemist Karel Hendrik Mertens originally synthesized the compound as a part of his doctoral dissertation published in 1877 by slowly mixing dimethylaniline with concentrated nitric acid in the presence of sulfuric acid, and it's still a viable lab technique. However, in the 1930s a more economical route was commercialized, where methylamine produced by the Smoleński method (developed after WWI) reacts with dinitrochlorobenzene to make dinitromethylaniline which is then easily nitrated without byproducts.

Health concerns

Although tetryl is among the most toxic explosive compounds, it is very short-lived, especially if in fact detonated. This combined with the fact that the health impacts of this compound are largely unstudied, not much is known about any health problems that this compound may cause.

Epidemiological data shows that tetryl has most effect on the skin, acting as a strong irritant. Symptoms of skin sensitization such as dermatitis, itch, erythema, etc. may occur. Tetryl can also affect mucous membranes, the upper respiratory tract, and possibly the liver.

References

• Cooper, Paul W., Explosives Engineering, New York: Wiley-VCH, 1996.

References

1. {{PGCH. 0607
2. {{IDLH. 479458. Tetryl
3. "Booster Explosives".
4. “A Military Guide to Terrorism in the 21st Century.” August 2003. P. 171. U.S. Army Training and Doctrine Command, Fort Leavenworth, Kansas. http://smallwarsjournal.com/documents/terrorismhandbook.pdf. Accessed May 11, 2010.
5. Mertens, Karel Hendrik. (1877). "Over nitroderivaten van dimethylaniline". S. C. Van Doesburgh.
6. [https://www.cdc.gov/niosh/idlh/479458.html CDC - Documentation for Immediately Dangerous To Life or Health Concentrations (IDLHs)]
7. [https://www.cdc.gov/niosh/npg/npgd0607.html CDC - NIOSH Pocket Guide to Chemical Hazards]