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Sodium pyrosulfate


Sodium pyrosulfate is an inorganic compound with the chemical formula of Na2S2O7. It hydrolyses in water to form sodium bisulfate with a chemical formula of NaHSO4 which has a pH of around 1.

Preparation

Sodium pyrosulfate is obtained by heating sodium bisulfate to 280 °C (536 °F)

: 2 NaHSO4 → Na2S2O7 + H2O

Temperatures above 460 °C further decompose the compound, producing sodium sulfate and sulfur trioxide:

: Na2S2O7 → Na2SO4 + SO3

Applications

Sodium pyrosulfate was used in analytical chemistry. Samples are fused with sodium pyrosulfate to ensure complete dissolution before a quantitative analysis.

References

References

  1. (1934). "Van Nostrand's Chemical Annual". Chapman and Hall.
  2. (1962). "Hydrolysis of Sodium Pyrosulfate". ACS.
  3. Helmold Plessen. (2000). "Sodium Sulfates". Wiley-VCH.
  4. (1913). "A Textbook of Chemistry". Henry Holt and Company.
  5. (2000). "Ullmann's Encyclopedia of Industrial Chemistry".
  6. (1969). "Analytical chemistry of boron: Analytical chemistry of the elements". Ann Arbor-Humphrey Science Publishers.
  7. (1965). "Quartz, Feldspar, and Mica Determination for Soils by Sodium Pyrosulfate Fusion". Soil Science Society of America Journal.
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