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Smoky quartz

Brown to black variety of quartz


Brown to black variety of quartz

FieldValue
nameSmoky quartz
categoryTectosilicate minerals
groupQuartz group
speciesQuartz
imageSmoky-quartz-TUCQTZ09-03-arkenstone-irocks.png
formulaSiO2
strunz04.DA.05
dana75.01.03.01
symmetryTrigonal 32
unit cella = 4.9133 Å, c = 5.4053 Å; Z=3
colourBrown, gray, black
habit6-sided prism ending in 6-sided pyramid (typical), drusy, fine-grained to microcrystalline, massive
systemα-quartz: trigonal trapezohedral class 3 2
β-quartz: hexagonal 622
twinningCommon Dauphine law, Brazil law and Japan law
cleavage{0110} none
fractureConchoidal
tenacityBrittle
mohs7 – lower in impure varieties (defining mineral)
lustreVitreous – waxy to dull when massive
refractivenω = 1.543–1.545
nε = 1.552–1.554
opticalpropUniaxial (+)
birefringence+0.009 (B-G interval)
pleochroismweak, from red-brown to yellow-brown
streakWhite
gravity2.65; variable 2.59–2.63 in impure varieties
melt1670 °C (β tridymite) 1713 °C (β cristobalite)
solubilityInsoluble at STP; 1 ppmmass at 400 °C and 500 lb/in2 to 2600 ppmmass at 500 °C and 1500 lb/in2
diaphaneityTransparent to nearly opaque
otherlattice: hexagonal, Piezoelectric, may be triboluminescent, chiral (hence optically active if not racemic)
references

β-quartz: hexagonal 622 nε = 1.552–1.554

Smoky quartz is a brown to black, translucent variety of quartz. It ranges in clarity from almost complete transparency to almost-opaque black crystals. Smoky quartz is popular as a gemstone and as a collectible crystal.

Properties

Smoky quartz ranges in color from brown or smoky gray to a nearly opaque black. The color of smoky quartz is produced when natural gamma radiation, emitted from the surrounding rock, activates color centers around aluminum impurities within the crystalline quartz. Smoky quartz is dichroic in polarized light and will fade in color if heated to above 200-300 C or exposed to UV light. It may turn a pale yellow color resembling citrine; some heat-treated smoky quartz is sold commercially as citrine. Gamma irradiation can restore color to faded smoky quartz crystals. Smoky quartz crystals that grew in certain environments such as pegmatites and alpine fissures tend to be evenly colored, while crystals originating in other environments tend to exhibit color zoning or phantoms. In some crystals, the color may be darker near the edges.

Varieties

Morion is a very dark brown to black opaque variety of smoky quartz. Morion is also the German name for smoky quartz. The name is from a misreading of mormorion in Pliny the Elder.

Cairngorm is a variety of smoky quartz found in the Cairngorm Mountains of Scotland. It usually has a smoky yellow-brown colour, though some specimens are greyish-brown. It is used in Scottish jewellery and as a decoration on kilt pins and the handles of sgianan-dubha (anglicised: sgian-dubhs or skean dhu).

Uses

Smoky quartz is common and was not historically important, but in recent times it has become a popular gemstone, especially for jewelry.

Sunglasses, in the form of flat panes of smoky quartz, were used in China in the 12th century.

References

References

  1. Deer, W. A., R. A. Howie and J. Zussman, ''An Introduction to the Rock Forming Minerals'', Logman, 1966, pp. 340–355 {{ISBN. 0-582-44210-9
  2. Berry, R. W., et al. “Quartz Cleavage and Quick Clays.” Science, vol. 184, no. 4133, 12 Apr. 1974, pp. 183–184, https://doi.org/10.1126/science.184.4133.183. Accessed 19 May 2025.
  3. (1990). "Handbook of Mineralogy". Mineralogical Society of America.
  4. "Quartz". Hudson Institute of Mineralogy.
  5. "Quartz Mineral Data".
  6. (1985). "Manual of Mineralogy". Wiley.
  7. "Smoky Quartz: A transparent brown gem & gem material".
  8. "Smoky Quartz". Hudson Institute of Mineralogy.
  9. "smoky quartz". Encyclopaedia Brittanica.
  10. "Citrine". Hudson Institute of Mineralogy.
  11. "Morion". Hudson Institute of Mineralogy.
  12. ''New Oxford American Dictionary'' (2nd ed., 2005), p. 1102.
  13. (12 June 2006). "The Nature of the Cairngorms: Diversity in a Changing Environment". The Stationery Office.
  14. {{Cite EB1911
  15. "The Gemstone Smoky Quartz".
  16. Joseph Needham, Science & Civilisation in China (Cambridge, England: Cambridge University Press, 1962), volume IV, part 1, page 121. Needham states that dark glasses were worn by Chinese judges to hide their facial expressions during court proceedings.
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