Silver iodide

Structure

The structure adopted by silver iodide is temperature dependent:

• Below 420 K, the β phase of AgI, with the wurtzite structure, is most stable. This phase is encountered in nature as the mineral iodargyrite.
• Above 420 K, the α phase becomes more stable. This motif is a body-centered cubic structure which has the silver centers distributed randomly between 6 octahedral, 12 tetrahedral and 24 trigonal sites. At this temperature, Ag+ ions can move rapidly through the solid, allowing fast ion conduction. The transition between the β and α forms represents the melting of the silver (cation) sublattice. The entropy of fusion for α-AgI is approximately half that for sodium chloride (a typical ionic solid). This can be rationalized by considering the AgI crystalline lattice to have already "partly melted" in the transition between α and β polymorphs.
• A metastable γ phase also exists below 420 K with the zinc blende structure. thumb|left|The golden-yellow crystals on this mineral sample are [[iodargyrite]], a naturally occurring form of β-AgI.

Preparation and properties

Silver iodide is prepared by reaction of an iodide solution (e.g., potassium iodide) with a solution of silver ions (e.g., silver nitrate). A yellowish solid quickly precipitates. The solid is a mixture of the two principal phases. Dissolution of the AgI in hydroiodic acid, followed by dilution with water, precipitates β-AgI. Alternatively, dissolution of AgI in a solution of concentrated silver nitrate followed by dilution affords α-AgI. Unless the preparation is conducted in dark conditions, the solid darkens rapidly, the light causing the reduction of ionic silver to metallic. The photosensitivity varies with sample purity.

Cloud seeding

The crystalline structure of β-AgI is similar to that of ice, allowing it to induce freezing by the process known as heterogeneous nucleation. Approximately 11,000 kg are used for cloud seeding annually, each seeding experiment consuming 10–50 grams.

Safety

Extreme exposure can lead to argyria, characterized by localized discolouration of body tissue.

References

Cited sources

References

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2. Haynes, p. 5.178
3. Haynes, p. 4.130
4. (1987). "Anharmonic thermal vibrations in wurtzite-type AgI". Acta Crystallographica Section B: Structural Science.
5. Haynes, p. 9.65
6. Haynes, p. 5.35
7. "C&L Inventory".
8. Binner, J. G. P.. (2006). "Hysteresis in the β–α Phase Transition in Silver Iodine". Journal of Thermal Analysis and Calorimetry.
9. Hull, Stephen. (2007). "Superionics: crystal structures and conduction processes". Rep. Prog. Phys..
10. O. Glemser, H. Saur "Silver Iodide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1036-7.
11. Phyllis A. Lyday "Iodine and Iodine Compounds" in Ullmann's Encyclopedia of Industrial Chemistry, p. 441. Wiley-VCH, Weinheim, 2005. {{doi. 10.1002/14356007.a14_381
12. "Silver Iodide". U.S. National Library of Medicine.