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Pentacarbon dioxide

Chemical compound


Chemical compound

Pentacarbon dioxide, officially penta-1,2,3,4-tetraene-1,5-dione, is an oxide of carbon (an oxocarbon) with formula C5O2 or O=C=C=C=C=C=O.

The compound was described in 1988 by Günter Maier and others, who obtained it by pyrolysis of 2,4,6-tris(diazo)cyclohexane-1,3,5-trione (C6N6O3). Diazo transfer can produce the latter compound from phloroglucinol. It is stable at room temperature in solution. The pure compound is stable up to −90 °C, at which point it polymerizes.

References

References

  1. (1988). "C5O2 (1,2,3,4-Pentatetraene-1,5-dione), a New Oxide of Carbon". Angewandte Chemie International Edition.
  2. Eastwood, F. W.. (1997). "Gas Phase Reactions in Organic Synthesis". CRC Press.
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