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Palladium tetrafluoride

| NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = Palladium(II,IV) fluoride

Palladium (IV) fluoride, also known as palladium tetrafluoride, is the chemical compound of palladium and fluorine with the chemical formula PdF4. The palladium atoms in PdF4 are in the +4 oxidation state.

Synthesis

Palladium tetrafluoride has been prepared by reacting palladium(II,IV) fluoride with fluorine gas at pressures around 7 atm and at 300 °C for several days.

Structure

Crystals are composed of octahedral PdF6 units, with four fluorides from each octahedron shared (bridging between octahedra).

Reactivity

PdF4 is a strong oxidising agent and undergoes rapid hydrolysis in moist air.

References

(1976). "The tetrafluorides of iridium, rhodium and palladium". J. Inorg. Nucl. Chem..
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Wright, Albert F.. (1978-03-01). "A neutron powder diffraction study of palladium tetrafluoride". Inorganic Chemistry.

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palladium-compounds fluorides platinum-group-halides

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