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Palladium(II,IV) fluoride

Palladium(II,IV) fluoride

| NFPA-H = | NFPA-F = | NFPA-R = | NFPA-S = Palladium(IV) fluoride

Palladium(II,IV) fluoride, also known as palladium trifluoride, is a chemical compound of palladium and fluorine. It has the empirical formula PdF3, but is better described as the mixed-valence compound palladium(II) hexafluoropalladate(IV), PdII[PdIVF6], and is often written as Pd[PdF6] or Pd2F6.

Synthesis

Pd[PdF6] is the most stable product of the reaction of fluorine and metallic palladium.

:2 Pd + 3 F2 → Pd[PdF6]

Structure and properties

Pd[PdF6] is paramagnetic, and both Pd(II) and Pd(IV) occupy octahedral sites in the crystal structure. The PdII-F distance is 2.17 Å, whereas the PdIV-F distance is 1.90 Å.

Coordination environments of Pd<sup>II</sup> and Pd<sup>IV</sup>, showing different distances to F atoms

References

References

  1. {{Greenwood&Earnshaw2nd
  2. {{Housecroft3rd
  3. (1957). "The crystal structures of the trifluorides of iron, cobalt, ruthenium, rhodium, palladium and iridium". [[Acta Crystallographica.
  4. (2001). "Preparation, Magnetic Properties, and Pressure-Induced Transitions of Some MIIMIVF6 (MII=Ni, Pd, Cu; MIV=Pd, Pt, Sn) Complex Fluorides". [[Journal of Solid State Chemistry.
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palladium-compounds fluorides platinum-group-halides mixed-valence-compounds
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