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Palladium fluoride

Palladium fluoride is the name of a series of binary compounds of palladium and fluorine. These include:

  • Palladium(II) fluoride or palladium difluoride, PdF2
  • Palladium(II,IV) fluoride or palladium trifluoride, PdF3. It is not palladium(III) fluoride (which is unknown), and is often described as palladium(II) hexafluoropalladate(IV), PdII[PdIVF6]
  • Palladium(IV) fluoride, or palladium tetrafluoride, PdF4
  • Palladium(VI) fluoride, or palladium hexafluoride, PdF6, which is calculated to be stable

Palladium-fluorine coordination complexes have been developed to catalyse the synthesis of aryl fluorides, which are otherwise difficult to make.

References

References

  1. {{Greenwood&Earnshaw2nd
  2. (2007). "On the Existence of Molecular Palladium(VI) Compounds: Palladium Hexafluoride". [[Inorganic Chemistry (journal).
  3. (2002). "Palladium Fluoride Complexes: One More Step toward Metal-Mediated C-F Bond Formation". [[Chem. Eur. J.]].
  4. (2009). "Formation of ArF from LPdAr(F): Catalytic Conversion of Aryl Triflates to Aryl Fluorides". [[Science (journal).
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palladium-compounds fluorides platinum-group-halides
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