Lithium peroxide

Preparation

It is prepared by the reaction of hydrogen peroxide and lithium hydroxide. This reaction initially produces lithium hydroperoxide: :LiOH + H2O2 → LiOOH + H2O This lithium hydroperoxide may exist as lithium peroxide monoperoxohydrate trihydrate (Li2O2·H2O2·3H2O). Dehydration of this material gives the anhydrous peroxide salt: :2 LiOOH → Li2O2 + H2O2

Li2O2 decomposes at about 450 °C to give lithium oxide: :2 Li2O2 → 2 Li2O + O2

The structure of solid Li2O2 has been determined by X-ray crystallography and density functional theory. The solid features eclipsed "ethane-like" Li6O2 subunits with an O-O distance of around 1.5 Å.

Uses

Air purification

It is used in air purifiers where weight is important, e.g., spacecraft or other sealed spaces and apparatuses to absorb carbon dioxide and release oxygen in the reaction:

Li2O2 + CO2 → Li2CO3 + O2

Similar to the reaction of lithium hydroxide with carbon dioxide to release 1 Li2CO3 and 1 H2O, lithium peroxide has high absorption capacity and absorbs more CO2 than does the same weight of lithium hydroxide and offers the bonus of releasing oxygen instead of water.

Styrene polymerization

Lithium peroxide can also act as a catalyst for polymerization of styrene to polystyrene. The polymerization of styrene to polystyrene typically involves the use of radical initiators via the free radical chain mechanism but lithium peroxide can also initiate radical polymerization reactions under certain conditions, although not as widely used.

Lithium-air battery

The reversible lithium peroxide reaction is the basis for a prototype lithium–air battery. Using oxygen from the atmosphere allows the battery to eliminate storage of oxygen for its reaction, saving battery weight and size.

References

References

1. [http://www.hbcpnetbase.com/pdf/default.asp?id=04_02_91 "Physical Constants of Inorganic Compounds,"] in CRC Handbook of Chemistry and Physics, 91st Edition (Internet Version 2011), W. M. Haynes, ed., CRC Press/Taylor and Francis, Boca Raton, Florida. (pp: 4-72).
2. Speight, James G. (2005). Lange's Handbook of Chemistry (16th Edition). (pp: 1.40). McGraw-Hill. Online version available at: http://www.knovel.com/web/portal/browse/display?_EXT_KNOVEL_DISPLAY_bookid=1347&VerticalID=0
3. Phys.Chem.Chem.Phys.,2013,15, 11025. {{doi. 10.1039/c3cp51056e
4. {{Greenwood&Earnshaw1st
5. E. Dönges "Lithium and Sodium Peroxides" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 979.
6. L. G. Cota and P. de la Mora "On the structure of lithium peroxide, Li₂O₂" Acta Crystallogr. 2005, vol. B61, pages 133-136. {{doi. 10.1107/S0108768105003629
7. Ulrich Wietelmann, Richard J. Bauer "Lithium and Lithium Compounds" in Ullmann's Encyclopedia of Industrial Chemistry 2005, Wiley-VCH: Weinheim. {{doi. 10.1002/14356007.a15_393.pub2
8. Girishkumar, G.. (July 2, 2010). "Lithium- air battery: Promise and challenges". The Journal of Physical Chemistry Letters.