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Isotopes of silicon

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Isotopes of silicon

none

Silicon (14Si) has 25 known isotopes, with mass number ranging from 22 to 46. 28Si (the most abundant isotope, at 92.24%), 29Si (4.67%), and 30Si (3.07%) are stable. The longest-lived radioisotope is 32Si, which occurs naturally in tiny quantities from cosmic ray spallation of argon. Its half-life has been determined to be approximately 157 years; it beta decays with energy 0.21 MeV to 32P, which in turn beta-decays, with half-life 14.269 days to 32S; neither step has gamma emission. After 32Si, 31Si has the second longest half-life at 157.2 minutes. All others have half-lives under 7 seconds.

A chart showing the relative abundances of the naturally occurring isotopes of silicon.

List of isotopes

|-id=Silicon-22 | β+, p (62%)

21Mg
β+ (37%)
22Al
-
β+, 2p (0.7%)
20Na
-id=Silicon-23
β+, p (88%)
22Mg
-
β+ (8%)
23Al
-
β+, 2p (3.6%)
21Na
-id=Silicon-24
β+ (65.5%)
24Al
-
β+, p (34.5%)
23Mg
-id=Silicon-25
β+ (65%)
25Al
-
β+, p (35%)
24Mg
-id=Silicon-26
26Si
25.99233382(12)
2.2453(7) s
β+
26Al
0+

| | |-id=Silicon-27 | 27Si | 26.98670469(12) | 4.117(14) s | β+ | 27Al | 5/2+ | | |- | 28Si | 27.97692653442(55) | 0+ | 0.92223(19)

0.92205–0.92241
29Si
28.97649466434(60)
1/2+
0.04685(8)
0.04678–0.04692
-id=Silicon-30
30Si
29.973770137(23)
0+
0.03092(11)
0.03082–0.03102
-id=Silicon-31
31Si
30.975363196(46)
157.16(20) min
β−
31P
3/2+

| | |-id=Silicon-32 | 32Si | 31.97415154(32) | 157(7) y | β− | 32P | 0+ | trace | cosmogenic |-id=Silicon-33 | 33Si | 32.97797696(75) | 6.18(18) s | β− | 33P | 3/2+ | | |- | 34Si | 33.97853805(86) | 2.77(20) s | β− | 34P | 0+ | | |-id=Silicon-34m | | IT | 34Si | (3−) | | |-id=Silicon-35 | β−

35P
β−, n?
34P
-id=Silicon-36
β− (88%)
36P
-
β−, n (12%)
35P
-id=Silicon-37
β− (83%)
37P
-
β−, n (17%)
36P
-
β−, 2n?
35P
-id=Silicon-38
β− (75%)
38P
-
β−, n (25%)
37P
-id=Silicon-39
β− (67%)
39P
-
β−, n (33%)
38P
-
β−, 2n?
37P
-id=Silicon-40
β− (62%)
40P
-
β−, n (38%)
39P
-
β−, 2n?
38P
-id=Silicon-41
β−, n (55%)
40P
-
β− (
41P
-
β−, 2n?
39P
-id=Silicon-42
β− (51%)
42P
-
β−, n (48%)
41P
-
β−, 2n (1%)
40P
-id=Silicon-43
β−, n (52%)
42P
-
β− (27%)
43P
-
β−, 2n (21%)
41P
-id=Silicon-44
β−?
44P
-
β−, n?
43P
-
β−, 2n?
42P
-id=Silicon-45
45Si
45.03982(64)#
4# ms

| | | 3/2−# | | |-id=Silicon-46 | 46Si | | | | | | |

Silicon-28

Silicon-28, the most abundant isotope of silicon, is of particular interest in the construction of quantum computers when highly enriched, as the presence of 29Si in a sample of silicon contributes to quantum decoherence. Extremely pure (99.9998%) samples of 28Si can be produced through selective ionization and deposition of 28Si from silane gas. Due to the extremely high purity that can be obtained in this manner, the Avogadro project sought to develop a new definition of the kilogram by making a 93.75 mm sphere of the isotope and determining the exact number of atoms in the sample.

Silicon-28 is produced in stars during the alpha process and the oxygen-burning process, and drives the silicon-burning process in massive stars shortly before they go supernova.

Silicon-29

Silicon-29 is of note as the only stable silicon isotope with a nonzero nuclear spin (I = 1/2). As such, it can be employed in nuclear magnetic resonance and hyperfine transition studies, for example to study the properties of the so-called A-center defect in pure silicon.

Silicon-34

Silicon-34 is a radioactive isotope with a half-life of 2.8 seconds. In addition to the usual N = 20 closed shell, the nucleus also shows a strong Z = 14 shell closure, making it behave like a doubly magic spherical nucleus, except that it is also located two protons above an island of inversion. Silicon-34 has an unusual "bubble" structure where the proton distribution is less dense at the center than near the surface, as the 2s1/2 proton orbital is almost unoccupied in the ground state, unlike in 36S where it is almost full. Silicon-34 is one of the known cluster decay emission particles; it is produced in the decay of 242Cm with a branching ratio of approximately .

References

References

  1. (2 July 2025). "Z = 14 Magicity Revealed by the Mass of the Proton Dripline Nucleus Si 22". Physical Review Letters.
  2. (2022). "Crossing ''N'' {{=}} 28 toward the neutron drip line: first measurement of half-lives at FRIB". Physical Review Letters.
  3. (2024). "Discovery of Neutron-Rich Silicon Isotopes 45,46Si". Oxford University Press (OUP).
  4. (2014-08-11). "Beyond Six Nines: Ultra-enriched Silicon Paves the Road to Quantum Computing". NIST.
  5. (2014-08-30). "Enriching 28 Si beyond 99.9998 % for semiconductor quantum computing". Journal of Physics D: Applied Physics.
  6. Powell, Devin (1 July 2008). [https://www.newscientist.com/article/dn14229-roundest-objects-in-the-world-created.html#.VOHyzfnRV_E "Roundest Objects in the World Created"]. ''[[New Scientist]]''. Retrieved 16 June 2015.
  7. "The Search for a More Perfect Kilogram".
  8. (2006). "The physics of core collapse supernovae". Nature Physics.
  9. Narlikar, Jayant V.. (1995). "From Black Clouds to Black Holes". [[World Scientific]].
  10. (1997). "Chemistry of the Elements". Butterworth-Heinemann.
  11. (1961-02-15). "Defects in Irradiated Silicon. I. Electron Spin Resonance of the Si- A Center". Physical Review.
  12. (11 September 2019). "Normal and intruder configurations in Si 34 populated in the β − decay of Mg 34 and Al 34". Physical Review C.
  13. (24 October 2016). "Physicists find atomic nucleus with a 'bubble' in the middle".
  14. (February 2017). "A proton density bubble in the doubly magic 34Si nucleus". Nature Physics.
  15. (2007). "Cluster radioactivity: an overview after twenty years". Romanian Reports in Physics.
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