Faujasite

Discovery and occurrence

Faujasite was first described in 1842 from an occurrence in the Limberg Quarries, Sasbach, Kaiserstuhl, Baden-Württemberg, Germany. The sodium modifier faujasite-Na was added following the discovery of the magnesium and calcium rich phases in the 1990s. It was named for Barthélemy Faujas de Saint-Fond (1741–1819), French geologist and volcanologist.

Faujasite occurs in vesicles within basalt and phonolite lava and tuff as an alteration or authigenic mineral. It occurs with other zeolites, olivine, augite and nepheline.

Structure

Synthesis

Faujasite is synthesized, as are other zeolites, from alumina sources such as sodium aluminate and silica sources such as sodium silicate. Other aluminosilicates such as kaolin are used as well. The ingredients are dissolved in a basic environment such as sodium hydroxide aqueous solution and crystallized at 70 to 300 °C (usually at 100 °C). After crystallization the faujasite is in its sodium form and must be ion exchanged with ammonium to improve stability. The ammonium ion is removed later by calcination which renders the zeolite in its acid form. Depending on the silica-to-alumina ratio of their framework, synthetic faujasite zeolites are divided into X and Y zeolites. In X zeolites that ratio is between 2 and 3, while in Y zeolites it is 3 or higher. The negative charges of the framework are balanced by the positive charges of cations (usually either sodium from the NaOH solution, or ammonium or H+ after exchanges) in non-framework positions. Such zeolites have ion-exchange, catalytic and adsorptive properties. The stability of the zeolite increases with the silica-to-alumina ratio of the framework (Lowenstein's rule). It is also affected by the type and amount of cations located in non-framework positions. For catalytic cracking, the Y zeolite is often used in a rare earth-hydrogen exchanged form.

By using thermal, hydrothermal or chemical methods, some of the alumina can be removed from the Y zeolite framework, resulting in high-silica Y zeolites. Such zeolites are used in cracking and hydrocracking catalysts. Complete dealumination results in faujasite-silica.

Use

Faujasite is used above all as a catalyst in fluid catalytic cracking to convert high-boiling fractions of petroleum crude to more valuable gasoline, diesel and other products. Zeolite Y has superseded zeolite X in this use because it is both more active and more stable at high temperatures due to the higher Si/Al ratio. It is also used in the hydrocracking units as a platinum/palladium support to increase aromatic content of reformulated refinery products.

Type X zeolite can be used to selectively adsorb CO2 from gas streams{{ cite patent

Due to its widely known structure, behaviour and properties, Faujasite is often used as a standard in catalytic and (ad/de)sorption studies on zeolites, along with MFI, FER and CHA

References

Literature

• Subhash Bhatia, Zeolite Catalysis: Principles and Applications, CRC Press, Inc., Boca Raton, Florida, 1990.
• Ribeiro, F. R., et al., ed., Zeolites: Science and Technology, Martinus Nijhoff Publishers, The Hague, 1984.

References

1. Warr, L.N.. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine.
2. [http://rruff.geo.arizona.edu/doclib/hom/faujasitena.pdf Faujasite]. Handbook of Mineralogy.
3. [http://www.mindat.org/min-6922.html Faujasite]. Mindat.
4. [http://webmineral.com/data/Faujasite-Ca.shtml Faujasite Mineral Data]. Webmineral.
5. [http://www.mindat.org/min-35126.html The Faujasite group on Mindat]
6. "FAU: Framework Type".
7. (1993). "Powder Neutron Diffraction and 29Si MAS NMR Studies of Siliceous Zeolite-Y". Journal of Solid State Chemistry.
8. "The Chemical Engineering Zeolite Page".
9. (1989). "Octane-Enhancing, Zeolitic FCC Catalysts: Scientific and Technical Aspects". Catalysis Reviews.
10. (2012-04-15). "Zeolites". Ullmann's Encyclopedia of Industrial Chemistry.
11. (2016-06-13). "Synthesis, characterisation, and catalytic evaluation of hierarchical faujasite zeolites: milestones, challenges, and future directions". Chemical Society Reviews.
12. "FER: Framework Type".
13. "CHA: Framework Type".
14. "MFI: Framework Type".