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Energy content of biofuel
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The energy content of biofuel is the chemical energy contained in a given biofuel, measured per unit mass of that fuel, as specific energy, or per unit of volume of the fuel, as energy density. A biofuel is a fuel produced from recently living organisms. Biofuels include bioethanol, an alcohol made by fermentation—often used as a gasoline additive, and biodiesel, which is usually used as a diesel additive. Specific energy is energy per unit mass, which is used to describe the chemical energy content of a fuel, expressed in SI units as joule per kilogram (J/kg) or equivalent units. Energy density is the amount of chemical energy per unit volume of the fuel, expressed in SI units as joule per litre (J/L) or equivalent units.
Different substances contain different amounts of potential energy, that is, the ability to do work.
To extract energy from a substance, a process must convert the substance into another state, releasing the potential energy as kinetic energy in the process, usually in the form of heat. Most man-made machines for harnessing this energy then convert the heat released into mechanical energy (such as a spinning turbine), then finally into electrical energy if needed, using a generator.
These machines vary in their effectiveness at capturing and harnessing the energy released. The proportion of energy usefully captured and converted into mechanical or electrical form is called its efficiency. No machines are 100% efficient. Thus the amount of useful work actually performed by these substances upon processing will never equal their potential energy content.
Furthermore, the mass and volume of a substance contributes to overhead energy costs for producing, processing, shipping, and storing of the substance required to utilize it as a fuel. When calculating economic or environmental impact of a particular fuel, all of these factors must be considered holistically.{{cite web |access-date=2008-05-18
Energy and CO2 output of common biofuels
The table below includes entries for popular substances already used for their energy, or being discussed for such use.
The second column shows specific energy, the energy content in megajoules per unit of mass in kilograms, useful in understanding the energy that can be extracted from the fuel.
The third column in the table lists energy density, the energy content per liter of volume, which is useful for understanding the space needed for storing the fuel.
The final two columns deal with the carbon footprint of the fuel. The fourth column contains the proportion of CO2 released when the fuel is converted for energy, with respect to its starting mass, and the fifth column lists the energy produced per kilogram of CO2 produced. As a guideline, a higher number in this column is better for the environment. But these numbers do not account for other green house gases released during burning, production, storage, or shipping. For example, methane may have hidden environmental costs that are not reflected in the table. https://web.archive.org/web/20070922180338/http://www.cypenv.org/worldenv/files/methane.htm
| Fuel type | Specific energy | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| (MJ/kg) | Energy Density | ||||||||||||
| (MJ/L) | CO2 Gas made from Fuel Used | ||||||||||||
| (kg/kg) | Energy per CO2 | ||||||||||||
| (MJ/kg) | Solid Fuels | Liquid Fuels | Gaseous Fuels | Fossil Fuels (comparison) | Nuclear fuels (comparison) | Fuel Cell Energy Storage (comparison) | Battery Energy Storage (comparison) | ||||||
| Bagasse (Cane Stalks) | 9.6 | ~+40%(C6H10O5)n+15% (C26H42O21)n+15% (C9H10O2)n1.30 | 7.41 | ||||||||||
| Chaff (Seed Casings) | 14.6 | [Please insert average composition here] | |||||||||||
| Animal Dung/Manure | [http://www.humanitarianinfo.org/darfur/uploads/idp/Cooking%20fuel%20-%20helpdoc%20by%20UNJLC.pdf](http://www.humanitarianinfo.org/darfur/uploads/idp/Cooking%20fuel%20-%20helpdoc%20by%20UNJLC.pdf) 10–[https://web.archive.org/web/20101126092443/http://home.hccnet.nl/david.dirkse/math/energy.html](https://web.archive.org/web/20101126092443/http://home.hccnet.nl/david.dirkse/math/energy.html) 15 | [Please insert average composition here] | |||||||||||
| Dried plants (C6H10O5)n | 10–16 | 1.6–16.64 | IF 50%(C6H10O5)*n*+25% (C26H42O21)*n*+25% (C10H12O3)*n*1.84 | 5.44-8.70 | |||||||||
| Wood fuel (C6H10O5)n | 16–21 | [http://www.fpl.fs.fed.us/documnts/fplgtr/fplgtr113/ch03.pdf](http://www.fpl.fs.fed.us/documnts/fplgtr/fplgtr113/ch03.pdf) 2.56–21.84 | IF 45%(C6H10O5)n+25% (C26H42O21)n+30% (C10H12O3)n1.88 | 8.51–11.17 | |||||||||
| Charcoal | 30 | 5.4–6.6 | 85–98% Carbon+VOC+Ash 3.63 | 8.27 | |||||||||
| Pyrolysis oil | 17.5 | 21.35 | varies | varies | |||||||||
| Methanol (CH3-OH) | 19.9–22.7 | 15.9 | 1.37 | 14.49–16.53 | |||||||||
| Ethanol (CH3-CH2-OH) | 23.4–26.8 | 18.4–21.2 | 1.91 | 12.25–14.03 | |||||||||
| Ecalene | 28.4 | 22.7 | 75%C2H6O+9%C3H8O+7%C4H10O+5%C5H12O+4%Hx 2.03 | 14.02 | |||||||||
| Butanol (CH3-(CH2)3-OH) | 36 | 29.2 | 2.37 | 15.16 | |||||||||
| Fat | 37.656 | 31.68 | C55H104O6 | ||||||||||
| Biodiesel | 37.8 | 33.3–35.7 | ~2.85 | ~13.26 | |||||||||
| Sunflower oil (C18H32O2) | [https://web.archive.org/web/20070927065241/http://www.pttplc.com/en/document/pdf/biofuel_en.pdf](https://web.archive.org/web/20070927065241/http://www.pttplc.com/en/document/pdf/biofuel_en.pdf) 39.49 | 33.18 | (12% (C16H32O2)+16% (C18H34O2)+71% (LA)+1% (ALA))2.81 | 14.04 | |||||||||
| Castor oil (C18H34O3) | [https://web.archive.org/web/20111113061656/http://www.castoroil.in/uses/fuel/castor_oil_fuel.html](https://web.archive.org/web/20111113061656/http://www.castoroil.in/uses/fuel/castor_oil_fuel.html) 39.5 | 33.21 | (1% PA+1% SA+89.5% ROA+3% OA+4.2% LA+0.3% ALA)2.67 | 14.80 | |||||||||
| Olive oil (C18H34O2) | 39.25–39.82 | 33–33.48 | (15% (C16H32O2)+75% (C18H34O2)+9% (LA)+1% (ALA))2.80 | 14.03 | |||||||||
| Methane (CH4) | 55–55.7 | (Liquefied) 23.0–23.3 | (Methane leak exerts 23 × greenhouse effect of CO2) 2.74 | 20.05–20.30 | |||||||||
| Hydrogen (H2) | 120–142 | (Liquefied) 8.5–10.1 | (Hydrogen leak slightly catalyzes ozone depletion) 0.0 | ||||||||||
| Coal | 29.3–33.5 | 39.85–74.43 | (Not Counting: CO, NOx, Sulfates & Particulates) ~3.59 | ~8.16–9.33 | |||||||||
| Crude Oil | 41.868 | 28–31.4 | (Not Counting: CO, NOx, Sulfates & Particulates) ~3.4 | ~12.31 | |||||||||
| Gasoline | 45–48.3 | 32–34.8 | (Not Counting: CO, NOx, Sulfates & Particulates) ~3.30 | ~13.64–14.64 | |||||||||
| Diesel | 48.1 | 40.3 | (Not Counting: CO, NOx, Sulfates & Particulates) ~3.4 | ~14.15 | |||||||||
| Natural Gas | 38–50 | (Liquefied) 25.5–28.7 | (Ethane, Propane & Butane Not Counting: CO, NOx & Sulfates) ~3.00 | ~12.67–16.67 | |||||||||
| Ethane (CH3-CH3) | 51.9 | (Liquefied) ~24.0 | 2.93 | 17.71 | |||||||||
| Uranium -235 (235U) | 77,000,000 | (Pure)1,470,700,000 | Greater for lower [ore conc.(Mining, Refining, Moving)] 0.0 | ~55 – ~90 | |||||||||
| Nuclear fusion (2H -3H) | 300,000,000 | (Liquefied)53,414,377.6 | (Sea-Bed Hydrogen-Isotope Mining-Method Dependent) 0.0 | ||||||||||
| Direct Methanol | 4.5466 | url=https://web.archive.org/web/20050911004117/http://uk.computers.toshiba-europe.com/cgi-bin/ToshibaCSG/news_article.jsp?service=UK&ID=0000005758 | date=2005-09-11 }} 3.6 | ~1.37 | ~3.31 | ||||||||
| Proton-Exchange (R&D) | up to 5.68 | up to 4.5 | (IFF Fuel is recycled) 0.0 | ||||||||||
| Sodium Hydride (R&D) | up to 11.13 | up to 10.24 | (Bladder for Sodium Oxide Recycling) 0.0 | ||||||||||
| Lead–acid battery | 0.108 | ~0.1 | (200–600 Deep-Cycle Tolerance) 0.0 | ||||||||||
| Nickel–iron battery | [https://web.archive.org/web/20061213172224/http://www.beutilityfree.com/batterynife/Flyer.pdf](https://web.archive.org/web/20061213172224/http://www.beutilityfree.com/batterynife/Flyer.pdf) 0.0487–0.1127 | 0.0658–0.1772 | ( | ||||||||||
| Nickel–cadmium battery | 0.162–0.288 | ~0.24 | (1k–1.5k Cycle Tolerance IF no Memory effect) 0.0 | ||||||||||
| Nickel–metal hydride | 0.22–0.324 | 0.36 | (300–500 Cycle Tolerance IF no Memory effect) 0.0 | ||||||||||
| Super-iron battery | 0.33 | NiMH]]) 0.54 | [http://www.sciencenews.org/articles/20040320/fob6.asp](http://www.sciencenews.org/articles/20040320/fob6.asp) (~300 Deep-Cycle Tolerance) 0.0 | ||||||||||
| Zinc–air battery | 0.396–0.72 | [https://web.archive.org/web/20060812091528/http://www.electric-fuel.com/evtech/index.shtml](https://web.archive.org/web/20060812091528/http://www.electric-fuel.com/evtech/index.shtml) 0.5924–0.8442 | (Recyclable by Smelting & Remixing, not Recharging) 0.0 | ||||||||||
| Lithium-ion battery | 0.54–0.72 | 0.9–1.9 | (3–5 y Life) (500-1k Deep-Cycle Tolerance) 0.0 | ||||||||||
| Lithium-Ion-Polymer | 0.65–0.87 | (1.2 * Li-Ion)1.08–2.28 | (3–5 y Life) (300–500 Deep-Cycle Tolerance) 0.0 | ||||||||||
| Lithium iron phosphate battery | |||||||||||||
| [DURACELL Zinc–Air](https://web.archive.org/web/20090127030703/http://www.duracell.com/oem/primary/Zinc/zinc_air_tech.asp) | 1.0584–1.5912 | 5.148–6.3216 | (1–3 y Shelf-life) (Recyclable not Rechargeable) 0.0 | ||||||||||
| Aluminium battery | 1.8–4.788 | 7.56 | (10–30 y Life) (3k+ Deep-Cycle Tolerance) 0.0 | ||||||||||
| [PolyPlusBC Li-Aircell](https://web.archive.org/web/20060321201937/http://www.polyplus.com/technology/technologyhome.htm) | 3.6–32.4 | 3.6–17.64 | (May be Rechargeable)(Might leak sulfates) 0.0 |
Notes
Yields of common crops associated with biofuels production
| Crop | Oil | |||||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| (kg/ha) | Oil | |||||||||||||||||||||||
| (L/ha) | Oil | |||||||||||||||||||||||
| (lb/acre) | Oil | |||||||||||||||||||||||
| (US gal/acre) | Oil per seeds | |||||||||||||||||||||||
| (kg/100 kg) | Melting Range (°C) | Iodine | ||||||||||||||||||||||
| number | Cetane | |||||||||||||||||||||||
| number | Oil / | |||||||||||||||||||||||
| Fat | Methyl | |||||||||||||||||||||||
| Ester | Ethyl | |||||||||||||||||||||||
| Ester | Crop | Oil | ||||||||||||||||||||||
| (kg/ha) | Oil | |||||||||||||||||||||||
| (L/ha) | Oil | |||||||||||||||||||||||
| (lb/acre) | Oil | |||||||||||||||||||||||
| (US gal/acre) | Oil per seeds | |||||||||||||||||||||||
| (kg/100 kg) | Melting Range (°C) | Iodine | ||||||||||||||||||||||
| number | Cetane | |||||||||||||||||||||||
| number | Oil / | |||||||||||||||||||||||
| Fat | Methyl | |||||||||||||||||||||||
| Ester | Ethyl | |||||||||||||||||||||||
| Ester | ||||||||||||||||||||||||
| Groundnut | (Kernel)42 | |||||||||||||||||||||||
| Copra | 62 | |||||||||||||||||||||||
| Tallow | 35–42 | 16 | 12 | 40–60 | 75 | |||||||||||||||||||
| Lard | 32–36 | 14 | 10 | 60–70 | 65 | |||||||||||||||||||
| Corn (maize) | 145 | 172 | 129 | 18 | -5 | -10 | -12 | 115–124 | 53 | |||||||||||||||
| Cashew nut | 148 | 176 | 132 | 19 | ||||||||||||||||||||
| Oats | 183 | 217 | 163 | 23 | ||||||||||||||||||||
| Lupine | 195 | 232 | 175 | 25 | ||||||||||||||||||||
| Kenaf | 230 | 273 | 205 | 29 | ||||||||||||||||||||
| Calendula | 256 | 305 | 229 | 33 | ||||||||||||||||||||
| Cotton | 273 | 325 | 244 | 35 | (Seed)13 | -1 – 0 | -5 | -8 | 100–115 | 55 | ||||||||||||||
| Hemp | 305 | 363 | 272 | 39 | ||||||||||||||||||||
| Soybean | 375 | 446 | 335 | 48 | 14 | -16 – -12 | -10 | -12 | 125–140 | 53 | ||||||||||||||
| Coffee | 386 | 459 | 345 | 49 | ||||||||||||||||||||
| Linseed (flax) | 402 | 478 | 359 | 51 | -24 | 178 | ||||||||||||||||||
| Hazelnuts | 405 | 482 | 362 | 51 | ||||||||||||||||||||
| Euphorbia | 440 | 524 | 393 | 56 | ||||||||||||||||||||
| Pumpkin seed | 449 | 534 | 401 | 57 | ||||||||||||||||||||
| Coriander | 450 | 536 | 402 | 57 | ||||||||||||||||||||
| Mustard seed | 481 | 572 | 430 | 61 | 35 | |||||||||||||||||||
| Camelina | 490 | 583 | 438 | 62 | ||||||||||||||||||||
| Sesame | 585 | 696 | 522 | 74 | 50 | |||||||||||||||||||
| Safflower | 655 | 779 | 585 | 83 | ||||||||||||||||||||
| Rice | 696 | 828 | 622 | 88 | ||||||||||||||||||||
| Tung oil tree | 790 | 940 | 705 | 100 | -2.5 | 168 | ||||||||||||||||||
| Sunflowers | 800 | 952 | 714 | 102 | 32 | -18 – -17 | -12 | -14 | 125–135 | 52 | ||||||||||||||
| Cocoa (cacao) | 863 | 1,026 | 771 | 110 | ||||||||||||||||||||
| Peanuts | 890 | 1,059 | 795 | 113 | 3 | 93 | ||||||||||||||||||
| Opium poppy | 978 | 1,163 | 873 | 124 | ||||||||||||||||||||
| Rapeseed | 1,000 | 1,190 | 893 | 127 | 37 | -10–5 | -10–0 | -12 – -2 | 97–115 | 55–58 | ||||||||||||||
| Olives | 1,019 | 1,212 | 910 | 129 | -12 – -6 | -6 | -8 | 77–94 | 60 | |||||||||||||||
| Castor beans | 1,188 | 1,413 | 1,061 | 151 | (Seed)50 | -18 | 85 | |||||||||||||||||
| Pecan nuts | 1,505 | 1,791 | 1,344 | 191 | ||||||||||||||||||||
| Jojoba | 1,528 | 1,818 | 1,365 | 194 | ||||||||||||||||||||
| Jatropha | 1,590 | 1,892 | 1,420 | 202 | ||||||||||||||||||||
| Macadamia nuts | 1,887 | 2,246 | 1,685 | 240 | ||||||||||||||||||||
| Brazil nuts | 2,010 | 2,392 | 1,795 | 255 | ||||||||||||||||||||
| Avocado | 2,217 | 2,638 | 1,980 | 282 | ||||||||||||||||||||
| Coconut | 2,260 | 2,689 | 2,018 | 287 | 20–25 | -9 | -6 | 8–10 | 70 | |||||||||||||||
| Chinese Tallow | 4,700 | 500 | ||||||||||||||||||||||
| Oil palm | 5,000 | 5,950 | 4,465 | 635 | 20–(Kernal)36 | 20–40 | -8–21 | -8–18 | 12–95 | 65–85 | ||||||||||||||
| Algae | 95,000 | 10,000 |
Notes
References
References
- 0881734357
- "The Two cap of SI Units and the SI Prefixes". NIST Guide to the SI.
- Intergovernmental Panel on Climate Change. (2007). "4.3.2 Nuclear energy". IPCC Fourth Assessment Report: Climate Change 2007, Working Group III Mitigation of Climate Change.
- Benjamin K. Sovacool.[http://www.nirs.org/climate/background/sovacool_nuclear_ghg.pdf Valuing the greenhouse gas emissions from nuclear power: A critical survey]. ''[[Energy Policy (journal). Energy Policy]]'', Vol. 36, 2008, p. 2950.
- Used with permission from [http://www.globalpetroleumclub.com The Global Petroleum Club].
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