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Dichloramine


Dichloramine (IUPAC name: Azonous dichloride) is a reactive inorganic compound with the chemical formula . It is one of the three chloramines of ammonia, the others being monochloramine () and nitrogen trichloride (). This yellow gas is unstable and reacts with many materials. It is formed by a reaction between ammonia and chlorine or sodium hypochlorite. It is a byproduct formed during the synthesis of monochloramine and nitrogen trichloride.

Synthesis

Dichloramine can be prepared by a reaction between monochloramine and chlorine or sodium hypochlorite:

:

Reactions

Dichloramine reacts with the hydroxide ion, which can be present in water or comes from water molecules, to yield nitroxyl and the chloride ion.

References

References

  1. Holleman-Wiberg: Lehrbuch der Anorganischen Chemie, 102. Auflage, Berlin 2007, {{ISBN. 978-3-11-017770-1.
  2. (1986). "The handbook of chlorination". Van Nostrand Reinhold.
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