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Curie (unit)

Non-SI unit of radioactivity


Non-SI unit of radioactivity

FieldValue
nameCurie
imageRadium226.jpg
captionA sample of radium, the element which was used in the original definition of the curie.
quantityActivity
symbolCi
namedafterPierre Curie and Marie Curie
units1rutherfords
inunits1
units2SI derived unit
inunits2
units3SI base unit
inunits3

The curie (symbol Ci) is a non-SI unit of radioactivity originally defined in 1910. According to a notice in Nature at the time, it was to be named in honour of Pierre Curie, but was considered at least by some to be in honour of Marie Skłodowska-Curie as well, and is in later literature considered to be named for both.

It was originally defined as "the quantity or mass of radium emanation in equilibrium with one gram of radium (element)", after more accurate measurements of the activity of Ra (which has a specific activity of ).

In 1975 the General Conference on Weights and Measures gave the becquerel (Bq), defined as one nuclear decay per second, official status as the SI unit of activity. Therefore: : 1 Ci = = 37 GBq and : 1 Bq ≅ ≅ 27 pCi

While its continued use is discouraged by the National Institute of Standards and Technology (NIST) and other bodies, the curie is still widely used throughout government, industry and medicine in the United States and in other countries.

At the 1910 meeting, which originally defined the curie, it was proposed to make it equivalent to 10 nanograms of radium (a practical amount). But Marie Curie, after initially accepting this, changed her mind and insisted on one gram of radium. According to Bertram Boltwood, Marie Curie thought that "the use of the name 'curie' for so infinitesimally small [a] quantity of anything was altogether inappropriate".

The power emitted in radioactive decay corresponding to one curie can be calculated by multiplying the decay energy by approximately 5.93 mW / MeV.

A radiotherapy machine may have roughly 1000 Ci of a radioisotope such as caesium-137 or cobalt-60. This quantity of radioactivity can produce serious health effects with only a few minutes of close-range, unshielded exposure.

Radioactive decay can lead to the emission of particulate radiation or electromagnetic radiation. Ingesting even small quantities of some particulate emitting radionuclides may be fatal. For example, the median lethal dose (LD-50) for ingested polonium-210 is 240 μCi; about 53.5 nanograms.

The typical human body contains roughly 0.1 μCi (14 mg) of naturally occurring potassium-40. A human body containing 16 kg of carbon (see Composition of the human body) would also have about 24 nanograms or 0.1 μCi of carbon-14. Together, these would result in a total of approximately 0.2 μCi or 7400 decays per second inside the person's body (mostly from beta decay but some from gamma decay).

As a measure of quantity

Units of activity (the curie and the becquerel) also refer to a quantity of radioactive atoms. Because the probability of decay is a fixed physical quantity, for a known number of atoms of a particular radionuclide, a predictable number will decay in a given time. The number of decays that will occur in one second in one gram of atoms of a particular radionuclide is known as the specific activity of that radionuclide.

The activity of a sample decreases with time because of decay.

The rules of radioactive decay may be used to convert activity to an actual number of atoms. They state that 1 Ci of radioactive atoms would follow the expression : N (atoms) × λ (s) = 1 Ci = 3.7 × 10 Bq, and so : N = 3.7 × 10 Bq / λ, where λ is the decay constant in s−1.

Here are some examples, ordered by half-life:

NuclideIsotopic mass (Da)Number of atoms in 1 gramHalf-lifeSpecific activity (Ci/g)Mass of 1 curie
209Bi208.98039862.8816773×10212.01×1019 years8.51×10−1711.7 billion tonnes
190Pt189.95994983.1702160×10214.83×1011 years3.90×10−9257 tonnes
147Sm146.91490444.0990673×10211.066×1011 years2.28×10−843.8 tonnes
232Th232.03805362.5953246×10211.405×1010 years1.10×10−7 (0.110 μCi/g)9.12 tonnes
238U238.05078762.5297714×10214.468×109 years3.36×10−7 (0.336 μCi/g)2.98 tonnes
40K39.963998171.50689146×10221.248×109 years7.18×10−6 (7.17 μCi/g)140 kg
235U235.04392812.5621342×10217.038×108 years2.16×10−6 (2.16 μCi/g)463 kg
129I128.90498364.6717672×10211.614×107 years1.72×10−4 (172 μCi/g)5.82 kg
99Tc98.906249686.0887363×10212.111×105 years1.71×10−458.4 g
239Pu239.05216162.5191744×10212.411×104 years6.20×10−216.1 g
240Pu240.05381172.5086628×10216561 years0.2274.41 g
14C14.003241994.30053323×10225700 years4.48223 mg
226Ra226.02540822.6643645×10211600 years0.9891.01 g
241Am241.05682732.4982245×1021432.6 years3.43292 mg
238Pu238.04955822.5297845×102187.7 years17.158.4 mg
137Cs136.90708934.3987063×102130.04 years86.911.5 mg
90Sr89.90772796.6981347×102128.91 years1387.27 mg
241Pu241.05684972.4982243×102114.329 years1049.66 mg
3H3.0160492813201.996698393×102312.32 years9.62×103104 μg
228Ra228.03106862.6409299×10215.75 years2733.67 mg
60Co59.933815541.00479849×10225.2714 years1.13×103884 μg
210Po209.98287372.8679200×1021138.376 days4.49×103223 μg
131I130.90612644.6003506×10218.0249 days1.24×1058.05 μg
123I122.90558984.8998103×102113.2232 hours1.93×106519 ng
212Pb211.99189592.8407410×102110.627 hours1.39×106719 ng
223Fr223.01973422.7002726×102122.00 minutes3.83×10726.1 ng
212Po211.98886802.8407816×1021294.4 nanoseconds1.81×10175.53 ag

References

References

  1. (6 October 1910). "Radium Standards and Nomenclature". Nature.
  2. (1996). "How the Curie Came to Be". Health Physics Society Newsletter.
  3. [[United States Atomic Energy Commission]]. (1951). "Semiannual Report of the Atomic Energy Commission, Volume 9".
  4. (1964). "Resolution 7 of the 12th CGPM". [[International Bureau of Weights and Measures]] (BIPM).
  5. (2002). "Radionuclide and Radiation Protection Data Handbook 2002". Nuclear Technology Publishing.
  6. (1975). "SI units for ionizing radiation: becquerel". Resolutions of the 15th CGPM.
  7. (28 January 2016). "NIST Special Publication 811, paragraph 5.2". NIST.
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