Cobalt(III) fluoride

Structure

Anhydrous

Anhydrous cobalt trifluoride crystallizes in the rhombohedral group, specifically according to the aluminium trifluoride motif, with a = 527.9 pm, α = 56.97°. Each cobalt atom is bound to six fluorine atoms in octahedral geometry, with Co–F distances of 189 pm. Each fluoride is a doubly bridging ligand.

Hydrates

A hydrate is known. It is conjectured to be better described as .

There is a report of an hydrate , isomorphic to .

Preparation

Cobalt trifluoride can be prepared in the laboratory by treating with fluorine at 250 °C: : + 3/2 → +
In this redox reaction, and are oxidized to and , respectively, while is reduced to . Cobalt(II) oxide (CoO) and cobalt(II) fluoride () can also be converted to cobalt(III) fluoride using fluorine.

The compound can also be formed by treating with chlorine trifluoride or bromine trifluoride .

Reactions

decomposes upon contact with water to give oxygen: :4 + 2 H2O → 4 HF + 4 Co + O2

It reacts with fluoride salts to give the anion [CoF6]3−, which is also features high-spin, octahedral cobalt(III) center.

Applications

is a powerful fluorinating agent. Used as slurry, converts hydrocarbons to the perfluorocarbons: :2 + R-H → 2 Co + R-F + HF Co is the byproduct.

Such reactions are sometimes accompanied by rearrangements or other reactions.

Gaseous {{chem2|CoF3}}

In the gas phase, is calculated to be planar in its ground state, and has a 3-fold rotation axis (point group D3h). The ion has a ground state of 3d6 5D. The fluoride ligands split this state into, in energy order, 5A', 5E", and 5E' states. The first energy difference is small and the 5E" state is subject to the Jahn-Teller effect, so this effect needs to be considered to be sure of the ground state. The energy lowering is small and does not change the energy order. This calculation was the first treatment of the Jahn-Teller effect using calculated energy surfaces.

References

References

1. Coe, P. L.. (2004). "Cobalt(III) Fluoride". J. Wiley.
2. Arthur W. Chester, El-Ahmadi Heiba, Ralph M. Dessau, and William J. Koehl Jr. (1969): "The interaction of cobalt(III) with chloride ion in acetic acid". ''Inorganic and Nuclear Chemistry Letters'', volume 5, issue 4, pages 277-283. {{doi. 10.1016/0020-1650(69)80198-4
3. H. F. Priest (1950): "Anhydrous Metal Fluorides". In ''Inorganic Syntheses'', McGraw-Hill, volume 3, pages 171-183. {{doi. 10.1002/9780470132340.ch47
4. W. Levason and C. A. McAuliffe (1974): "Higher oxidation state chemistry of iron, cobalt, and nickel". ''Coordination Chemistry Reviews'', volume 12, issue 2, pages 151-184. {{doi. 10.1016/S0010-8545(00)82026-3
5. The related reagent KCoF₄ is more selective.Coe, P. L. "Potassium Tetrafluorocobaltate(III)" in Encyclopedia of Reagents for Organic Synthesis (Ed: L. Paquette) 2004, J. Wiley & Sons, New York. {{doi. 10.1002/047084289X.rp251.
6. (1979). "Molecular and Electronic Structure of Transition Metal Trifluorides". J. Chem. Phys..