Cobalt(II) hydroxide

Preparation

Cobalt(II) hydroxide precipitates as a solid when an alkali metal hydroxide is added to an aqueous solution of Co2+ salt. For example, :Co2+ + 2 NaOH → Co(OH)2 + 2 Na+

The compound can be prepared by reacting cobalt(II) nitrate in water with a solution of triethylamine as both the base and a complexing agent.

Reactions

Cobalt(II) hydroxide decomposes to cobalt(II) oxide at 168 °C under vacuum and is oxidized by air.

Like iron(II) hydroxide, cobalt(II) hydroxide is a basic hydroxide, and reacts with acids to form cobalt(II) salts. It also reacts with strong bases to form solutions with dark blue cobaltate(II) anions, [Co(OH)4]2− and [Co(OH)6]4−.

Structure

The (β) form of cobalt(II) hydroxide has the brucite crystal structure, i.e. the arrangement of the atoms in the crystal are the same as the arrangement of the atoms in Mg(OH)2. The Co(II) centers are bonded to six hydroxide ligands. Each hydroxide ligand bridges to three Co(II) sites. The O-H bonds are perpendicular to the planes defined by the oxygen atoms, projecting above and below these layers. Ignoring the H atoms, the packing of the anion and cations is also described as the cadmium iodide structure, in which the cobalt(II) cations have octahedral molecular geometry.

The beta form can be obtained as platelets with partial hexagonal geometry, 100-300 nm wide and 5-10 nm thick.

Alpha form

The so-called "alpha form" (α-Co(OH)2) is not a polymorph of the pure (β) form, but rather a more complex compound in which hydroxide-cobalt-hydroxide layers have a residual positive charge and alternate with layers of other anions such as nitrate, carbonate, chloride, etc. (the hydrotalcite structure).

Nanotubes

Cobalt hydroxide can be obtained in the form of nanotubes, which may be of interest in nanotechnology and materials science.

References

References

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3. O. Glemser "Cobalt(II) Hydroxide" in Handbook of Preparative Inorganic Chemistry, 2nd Ed. Edited by G. Brauer, Academic Press, 1963, NY. Vol. 1. p. 1521.
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9. (2015). "General synthesis of inorganic single-walled nanotubes". Nature Communications.