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Chromium(III) 2-ethylhexanoate

Chromium(III) 2-ethylhexanoate

2-Ethylhexanoic acid chromium(III) salt AR-1I2320 CID103012

Chromium(III) 2-ethylhexanoate, C24H45CrO6, is a coordination complex of chromium and ethylhexanoate. In combination with 2,5-dimethylpyrrole it forms the Phillips selective ethylene trimerisation catalyst (not to be confused with Phillips catalyst), used in the industrial production of linear alpha olefins, particularly 1-hexene or 1-octene.

References

References

  1. Venderbosch, Bas; Oudsen, Jean-Pierre H.; Wolzak, Lukas A.; Martin, David J. ; Korstanje, Ties J.; Tromp, Moniek. Spectroscopic Investigation of the Activation of a Chromium-Pyrrolyl Ethene Trimerization Catalyst. ACS Catalysis (2019), 9(2), 1197-1210. {{doi. 10.1021/acscatal.8b03414.
  2. {{PGCH. 0141
  3. (24 May 2018). "Exploring Basic Components Effect on the Catalytic Efficiency of Chevron-Phillips Catalyst in Ethylene Trimerization". Catalysts.
  4. (April 2011). "Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations". Coordination Chemistry Reviews.
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chromium(iii)-compounds ethylhexanoates chromium-complexes
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