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Chromium acetate hydroxide

Chromium(III)acetatehydroxide,Cr24%, Chromic acetate hydroxide, Chromium - acetic acid (3:7) dihydrate, Chromium Acetic Acid, Ccris 6345,

Chromium acetate hydroxide is the coordination complex with the formula [Cr2(OH)3(OAc)3]4. A dark violet solid, it crystallizes as the triacontatetrahydrate (34 molecules of water of crystallization). It is water soluble.

Structure

The complex is a tetramer of binuclear Cr2(OH)3(OAc)3. The subunits are linked by acetate and hydroxide ligands. The oxidation state of chromium is +3, which explains the stability of the complex since octahedral d3 ions give kinetically robust complexes. Overall, the complex's structure is unusual compared to other transition metal carboxylate complexes.

References

References

  1. (2000). "Polynuclear Chromium(III) Carboxylates. 1. Synthesis, Structure, and Magnetic Properties of an Octanuclear Complex with a Ring Structure". Inorganic Chemistry.
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chromium(iii)-compounds acetates hydroxides coordination-complexes reducing-agents chromium–oxygen-compounds
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