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Chlorine perchlorate

Chlorine perchlorate is a chemical compound with the formula . This chlorine oxide is an asymmetric oxide, with one chlorine atom in +1 oxidation state and the other +7, with proper formula . It is produced by the photodimerization of chlorine dioxide () at room temperature by 436 nm ultraviolet light:

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Chlorine perchlorate can also be made by the following reaction at −45 °C.

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Properties

Chlorine perchlorate is a pale greenish liquid. It is less stable than (chlorine dioxide) and decomposes at room temperature to give (oxygen), (chlorine) and (dichlorine hexoxide):

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Chlorine perchlorate reacts with metal chlorides to form chlorine and the corresponding anhydrous perchlorate:

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Reactions

ReactantConditionsProducts
—Heatdichlorine hexoxide (80%), chlorine dioxide, chlorine, oxygen
—Ultraviolet lightdichlorine heptoxide, chlorine, oxygen
caesium iodide−45 °Ccaesium tetraperchloratoiodate(III)
or ClF—(M = Cs or [](nitronium))
bromine−45 °Cbromine perchlorate ()
iodine(0.33 mol)−50 °Ciodine(III) perchlorate
CF3I-112 °CCF3OClO3, , Cl2, , and .

Notes

References

References

  1. "Chloro Perchlorate - PubChem Public Chemical Database". National Center for Biotechnology Information.
  2. [https://pubchem.ncbi.nlm.nih.gov/compound/chlorine_perchlorate nih.gov]
  3. (1982). "Chlorine perchlorate a major photolysis product of chlorine dioxide". J. Phys. Chem..
  4. (1988). "Ultraviolet spectrum of chlorine perchlorate". J. Phys. Chem..
  5. (2010-04-15). "Perchlorate Formation by Ozone Oxidation of Aqueous Chlorine/Oxy-Chlorine Species: Role of ClxOy Radicals". Environmental Science & Technology.
  6. (1988). "The synthesis and properties of covalent organic perchlorates". Turpion.
  7. (1972). "Iodine tris­(perch1orate) and cesium tetrakis­(perchlorato)­iodate(III)". Inorganic Chemistry.
  8. (1975). "Halogen perchlorates: Reactions with fluorocarbon halides". Inorganic Chemistry.
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chlorine-oxides acidic-oxides chlorine(vii)-compounds perchlorates
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