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Cetyl alcohol

Soluble in acetone. Slightly soluble in alcohol. | NFPA-H = 1 | NFPA-F = 1 | NFPA-R = 0

Cetyl alcohol , also known as hexadecan-1-ol and palmityl alcohol, is a C-16 fatty alcohol with the formula CH3(CH2)15OH. At room temperature, cetyl alcohol takes the form of a waxy white solid or flakes. The name cetyl refers to whale oil (cetacea oil, from , from ) from which it was first isolated.

Preparation

Cetyl alcohol was discovered in 1817 by the French chemist Michel Chevreul when he heated spermaceti, a waxy substance obtained from sperm whale oil, with caustic potash (potassium hydroxide). Flakes of cetyl alcohol were left behind on cooling. Modern production is based around the chemical reduction of ethyl palmitate.

Occurrence and uses

The ether chimyl alcohol, derived from cetyl alcohol and glycerol, is a component of some lipid membranes.

Cetyl alcohol is used in the cosmetic industry as an opacifier in shampoos, or as an emollient, emulsifier or thickening agent in the manufacture of skin creams and lotions. It is also employed as a lubricant for nuts and bolts, and is the active ingredient in some "liquid pool covers" (forming a non-volatile surface layer to reduce water evaporation, related latent vaporization heat loss, and thus to retain heat in the pool). Moreover, it can also be used as a non-ionic co-surfactant in emulsion applications.

Side effects

People who have eczema can be sensitive to cetyl alcohol, though this may be due to impurities rather than cetyl alcohol itself. However, cetyl alcohol is sometimes included in medications used for the treatment of eczema.

References

References

  1. ''[[Merck Index]]'', 11th Edition, '''2020'''.
  2. "Hexadecan-1-ol_msds".
  3. (2001). "A guide to the pronunciation and meaning of cetacean taxonomic names". Aquatic Mammals.
  4. Nordegren, Thomas. (2002). "The A-Z Encyclopedia of Alcohol and Drug Abuse". Universal Publishers.
  5. Booth, James Curtis. (1862). "The Encyclopedia of Chemistry, Practical and Theoretical". Philadelphia, H.C. Baird.
  6. (July 20, 1998). "Cetyl alcohol".
  7. Smolinske, Susan C. (1992). "Handbook of Food, Drug, and Cosmetic Excipients". CRC Press.
  8. (April 2006). "Selection of surfactants for stable paraffin-in-water dispersions, undergoing solid−liquid transition of the dispersed particles". Langmuir.
  9. (1969). "Dermatitis from cetyl and stearyl alcohols". Archives of Dermatology.
  10. (1997). "A case of contact dermatitis due to impurities of cetyl alcohol". Contact Dermatitis.
  11. Kato N. (1987). "Contact dermatitis due to Japanese pharmacopeia cetyl alcohol". Skin Research.
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fatty-alcohols antioxidants non-ionic-surfactants lubricants cosmetics-chemicals whale-products primary-alcohols alkanols semiochemicals insect-pheromones
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