Bromine trifluoride

Synthesis

Bromine trifluoride was first described by Paul Lebeau in 1906, who obtained the material by the reaction of bromine with fluorine at 20 °C:

:

The disproportionation of bromine monofluoride also gives bromine trifluoride:

:

Structure

Like ClF3 and IF3, the BrF3 molecule is T-shaped and planar. In the VSEPR formalism, the bromine center is assigned two electron lone pairs. The distance from the bromine atom to each axial fluorine atom is 1.81 Å and to the equatorial fluorine atom is 1.72 Å. The angle between an axial fluorine atom and the equatorial fluorine atom is slightly smaller than 90° — the 86.2° angle observed is due to the repulsion generated by the electron pairs being greater than that of the Br-F bonds.

Chemical properties

In a highly exothermic reaction, BrF3 reacts with water to form hydrobromic acid and hydrofluoric acid:

:

BrF3 is a fluorinating agent, but less reactive than ClF3. Already at −196 °C, it reacts with acetonitrile to give 1,1,1-trifluoroethane.

: + Br2 + N2

The liquid is conducting, owing to autoionisation:

:

Fluoride salts dissolve readily in BrF3 forming tetrafluorobromate:

:

It reacts as a fluoride donor:A. J. Edwards and G. R. Jones. J. Chem. Soc. A, 1467 (1969)

:

References

References

1. "Safety Data Sheet : Bromine Trifluoride".
2. {{RubberBible87th
3. "Archived copy".
4. "Safety Data Sheet Bromine Trifluoride". Airgas.
5. {{Greenwood&Earnshaw
6. Lebeau P.. (1906). "The effect of fluorine on chloride and on bromine". [[Annales de Chimie et de Physique]].
7. Simons JH. (1950). "Bromine (III) Fluoride - Bromine Trifluoride".
8. Gutmann V. (1950). "Die Chemie in Bromitrifluorid". Angewandte Chemie.
9. Meinert H. (1967). "Interhalogenverbindungen". Zeitschrift für Chemie.
10. (2007). "Encyclopedia of Reagents for Organic Synthesis".
11. (2010). "Selective Reactions of Bromine Trifluoride in Organic Chemistry". Advanced Synthesis & Catalysis.