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Anilinium chloride

| NFPA-H = 3 | NFPA-F = 1 | NFPA-R = 0 | NFPA-S =

Anilinium chloride is the organic compound with the formula . It is a white solid and the chloride salt of anilinium, which is the conjugate acid of aniline, . Anilinium chloride is produced by treatment of aniline with hydrochloric acid. The cation consists of a phenyl ring attached to a tetrahedral ammonium center. The C-N bond elongates from 1.41 Å in aniline to 1.474 Å in anilinium.

Uses

Anilinium chloride is used as a precursor to diphenylamine by heating with aniline: :

It reacts with formaldehyde to give methylenedianiline, a precursor to commercial polymers.

References

References

  1. "Aniline hydrochloride".
  2. (2006). "Unusual variations in the incidence of Z? > 1 in oxo-anion structures". Chemical Communications.
  3. (2003). "Kirk-Othmer Encyclopedia of Chemical Technology".
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ammonium-compounds anilines
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