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Andradite

Nesosilicate mineral species of garnet

Andradite

Nesosilicate mineral species of garnet

FieldValue
nameAndradite [Adr]
categoryGarnet group
imageAndradite-Mali.jpg
imagesize260px
captionSingle crystal (4.2cm) – Diakon, Nioro du Sahel Circle, Kayes Region, Mali
formulaCa3Fe2(SiO4)3
IMAsymbolAdr
strunz9.AD.25
systemCubic
classHexoctahedral (mm)
H-M symbol: (4/m 2/m)
symmetry*I*ad
unit cella = 12.056 Å; Z = 8
colorYellow, greenish yellow to emerald-green, dark green; brown, brownish red, brownish yellow; grayish black, black; may be sectored
habitCommonly well-crystallized dodecahedra, trapezohedra, or combinations, also granular to massive
cleavagenone
fractureconchoidal to uneven
tenacityBrittle
mohs6.5 to 7
lusterAdamantine to resinous, dull
diaphaneityTransparent to translucent
refractiven = 1.887
opticalpropIsotropic, typically weakly anisotropic
absorptiondemantoid – 440nm band or complete absorption at 440nm and below, may also have lines at 618, 634, 685, 690nm
streakWhite
gravity3.859 calculated; 3.8–3.9 measured
references
var1Demantoidvar1text = transparent light to dark green to yellow-green
var2*Melanite*var2text = opaque black
var3*Topazolite*var3text = transparent to translucent yellow, may show chatoyancy

H-M symbol: (4/m 2/m)

Andradite garnet - Jiangxi, Nantan, China.

Andradite is a mineral species of the garnet group. It is a nesosilicate, with chemical formula Ca3Fe2Si3O12.

Andradite includes four varieties:

  • Colophonite: a historical variety found in the Scandinavian islands, brownish or reddish in color, often opaque or translucent.
  • Demantoid: Vivid green in color, one of the most valuable and rare stones in the gemological world.
  • Melanite: Black in color due to limited substitution of titanium for iron. Also known as "titanian andradite". Forms a solid solution with morimotoite and schorlomite depending on titanium and iron content.
  • Topazolite: Yellow-green in color and sometimes of high enough quality to be cut into a faceted gemstone, it is rarer than demantoid.

It was first described in 1868 for an occurrence in Drammen, Buskerud, Norway. Andradite was named after the Brazilian statesman, naturalist, professor and poet José Bonifácio de Andrada e Silva (1763–1838).

Occurrence

It occurs in skarns developed in contact metamorphosed impure limestones or calcic igneous rocks; in chlorite schists and serpentinites and in alkalic igneous rocks (typically titaniferous). Associated minerals include vesuvianite, chlorite, epidote, spinel, calcite, dolomite and magnetite. It is found in Iran, Italy, the Ural Mountains of Russia, Arizona and California and in Dnipropetrovsk Oblast in Ukraine.

Like the other garnets, andradite crystallizes in the cubic space group 3}}d, with unit-cell parameter of 12.051 Å at 100 K.

The spin structure of andradite contains two mutually canted equivalent antiferromagnetic sublattices below the Néel temperature (TN=11 K).

File:Mélanite-Mali.jpg|Black crystals of andradite: melanite

References

References

  1. Warr, L.N.. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine.
  2. Gemological Institute of America, ''GIA Gem Reference Guide'' 1995, {{ISBN. 0-87311-019-6
  3. ''[http://rruff.geo.arizona.edu/doclib/hom/andradite.pdf Handbook of Mineralogy]''
  4. [http://www.mindat.org/min-223.html Andradite], Mindat.org
  5. [http://www.webmineral.com/data/Andradite.shtml Webmineral data]
  6. ''Olga Bortnik''. All about precious stones. ― Moscow: Harvest, 2011.
  7. (2009). "Gems and Gemstones: Timeless Natural Beauty of the Mineral World". University of Chicago Press.
  8. [http://www.mindat.org/min-7443.html Melanite], Mindat.org
  9. Thomas Armbruster and Charles A. Geiger (1993): "[http://eurjmin.geoscienceworld.org/cgi/content/abstract/5/1/59 Andradite crystal chemistry, dynamic X-site disorder and structural strain in silicate garnets]." ''European Journal of Mineralogy'' v. 5, no. 1, p. 59-71.
  10. Universal Publishers]]/Dissertation.com, Boca Raton, Florida, USA, p. 136. {{ISBN. 1-59942-316-2.
  11. Enver Murad (1984): "[http://ammin.geoscienceworld.org/cgi/content/abstract/69/7-8/722 Magnetic ordering in andradite]." ''American Mineralogist'' 69, no. 7-8; pp. 722–24.
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