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4-Bromoaniline

4-Bromoaniline is a compound where an aniline molecule is substituted with a bromine atom on the para position. Commercially available, this compound may be used as a building block, e.g. in the preparation of monobrominated biphenyl via the Gomberg–Bachmann reaction.

Preparation

4-Bromoaniline can be made by reacting acetyl chloride-protected aniline with bromine.

Reactions

One laboratory route to 1-bromo-4-iodobenzene involves the Sandmeyer reaction. 4-Bromoaniline is treated with concentrated sulfuric acid and sodium nitrite, then potassium iodide.

References

[http://www.chemblink.com/products/106-40-1.htm 4-Bromoaniline], Chemblink.com
[[Moses Gomberg. (1941). "p-Bromobiphenyl".
(15 January 2009). "Synthesis, Optical, and Electronic Properties of Soluble Poly-p-phenylene Oligomers as Models for Molecular Wires". [[Journal of the American Chemical Society]].

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4-aminophenyl-compounds 4-bromophenyl-compounds

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