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2-hydroxyethylphosphonate dioxygenase

Class of enzymes


Class of enzymes

FieldValue
Name2-hydroxyethylphosphonate dioxygenase
EC_number1.13.11.72

2-hydroxyethylphosphonate dioxygenase (, HEPD, phpD (gene)) is an enzyme with systematic name 2-hydroxyethylphosphonate:O2 1,2-oxidoreductase (hydroxymethylphosphonate forming). This enzyme catalyses the following chemical reaction

: 2-hydroxyethylphosphonate + O2 \rightleftharpoons hydroxymethylphosphonate + formate

2-hydroxyethylphosphonate dioxygenase contains non-heme-Fe(II).

References

References

  1. (June 2009). "An unusual carbon-carbon bond cleavage reaction during phosphinothricin biosynthesis". Nature.
  2. (March 2011). "On the stereochemistry of 2-hydroxyethylphosphonate dioxygenase". Journal of the American Chemical Society.
  3. (August 2011). "Mechanism and substrate recognition of 2-hydroxyethylphosphonate dioxygenase". Biochemistry.
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