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(1,1'-Bis(diphenylphosphino)ferrocene)palladium(II) dichloride

Chemical compound

Chemical compound

[1,1'‑Bis(diphenylphosphino)ferrocene]palladium(II) dichloride is a palladium complex containing the bidentate ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf), abbreviated as [(dppf)PdCl]. This commercially available material can be prepared by reacting dppf with a suitable nitrile complex of palladium dichloride:

:dppf + PdCl(RCN) → (dppf)PdCl + 2 RCN (RCN = CHCN or CHCN)

The compound is popularly used for palladium-catalyzed coupling reactions, such as the Buchwald–Hartwig amination and the reductive homocoupling of aryl halides.

References

References

  1. (2009). "Synthesis and Characterization of Transition-Metal Complexes Containing 1,1'-Bis(diphenylphosphino)ferrocene". [[J. Chem. Educ.]].
  2. (2015). "Reactions of the 21st Century: Two Decades of Innovative Catalyst Design for Palladium-Catalyzed Cross-Couplings". [[Organometallics]].
  3. (2007). "Modern Organic Synthesis in the Laboratory: A Collection of Standard Experimental Procedures". [[Oxford University Press]].
  4. (1996). "An Improved Catalyst System for Aromatic Carbon-Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates". [[J. Am. Chem. Soc.]].
  5. (2010). "Palladium-Catalyzed Reductive Homocoupling of Aromatic Halides and Oxidation of Alcohols". [[J. Org. Chem.]].
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palladium-compounds phosphine-complexes catalysts ferrocenes chloro-complexes
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