Pentazolate

In chemistry, a pentazolate is a compound that contains a cyclo-N5− ion, the anion of pentazole. In 2017, researchers prepared the first salt (N5)6(H3O)3(NH4)4Cl containing pentazolate anion starting a substituted phenylpentazole, m-CPBA and iron(II) glycinate. A series of metal and nonmetal pentazolates were subsequently synthesized according to their work.

.mw-parser-output .ib-chembox{border-collapse:collapse;text-align:left}.mw-parser-output .ib-chembox td,.mw-parser-output .ib-chembox th{border:1px solid #a2a9b1;width:40%}.mw-parser-output .ib-chembox td+td{width:60%}@media screen{html.skin-theme-clientpref-night .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}@media screen and (prefers-color-scheme:dark){html.skin-theme-clientpref-os .mw-parser-output .ib-chembox figure:not(.skin-invert-image):not(.skin-invert):not(.bg-transparent){background:var(--background-color-inverted,#f8f9fa)}}

Column 1Column 2
CAS Number.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}86840-63-3 Y
3D model (JSmol)Interactive image
PubChem CID59450521
InChI
InChI=1S/N5/c1-2-4-5-3-1/q-1Key: DAHQTMWHOQRXRN-UHFFFAOYSA-N
SMILES
N1=NN=N[N-]1
Chemical formulaN5−1
Molar mass70.036 g·mol−1
Conjugate acidPentazole
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references | |

Precursors to pentazolates. (R=3,5-dimethyl-4-hydroxylphenyl)

In chemistry, a pentazolate is a compound that contains a cyclo-N5− ion, the anion of pentazole. In 2017, researchers prepared the first salt (N5)6(H3O)3(NH4)4Cl containing pentazolate anion starting a substituted phenylpentazole, m-CPBA and iron(II) glycinate. A series of metal and nonmetal pentazolates were subsequently synthesized according to their work.

AppearanceDec. temp (°C)Ref
LiN5white133
LiN5·3H2Ocolorless139
[Na(N5)(H2O)]·2H2Ocolorless111.3
[Mg(N5)2(H2O)6]·4H2Ocolorless103.5
Al(H2O)6(N5)3·9H2Owhite141.4
[Mn(N5)2(H2O)4]·4H2Ocolorless104.1
[Fe(N5)2(H2O)4]·4H2Opale green114.7
Fe(H2O)6(N5)3·9H2Oreddish brown108.9
[Co(N5)2(H2O)4]·4H2Obright orange58.9
AgN5pale white120
[Pb(OH)]4(N5)4colorless80
[N(CH3)4]N5white80.8
(NH3OH)N5white104.3
[C(NH2)3]N5white88.1
NH4N5white102.0
N2H5N5white85.3
(CN7H6)N596.3

.mw-parser-output .reflist-columns-2{column-width:30em}.mw-parser-output .reflist-columns-3{column-width:25em}body.skin-vector-2022 .mw-parser-output .reflist-columns-2{column-width:27em}body.skin-vector-2022 .mw-parser-output .reflist-columns-3{column-width:22.5em}.mw-parser-output .references[data-mw-group=upper-alpha]{list-style-type:upper-alpha}.mw-parser-output .references[data-mw-group=upper-roman]{list-style-type:upper-roman}.mw-parser-output .references[data-mw-group=lower-alpha]{list-style-type:lower-alpha}.mw-parser-output .references[data-mw-group=lower-greek]{list-style-type:lower-greek}.mw-parser-output .references[data-mw-group=lower-roman]{list-style-type:lower-roman}.mw-parser-output div.reflist-liststyle-upper-alpha .references{list-style-type:upper-alpha}.mw-parser-output div.reflist-liststyle-upper-roman .references{list-style-type:upper-roman}.mw-parser-output div.reflist-liststyle-lower-alpha .references{list-style-type:lower-alpha}.mw-parser-output div.reflist-liststyle-lower-greek .references{list-style-type:lower-greek}.mw-parser-output div.reflist-liststyle-lower-roman .references{list-style-type:lower-roman}

  • Azide (N3−)
  • Diazenide (N22−)
  • Nitride (N3−)