Bromisoval

Bromisoval (INN), commonly known as bromovalerylurea, is a hypnotic and sedative of the bromoureide group discovered by Knoll in 1907 and patented in 1909. It is marketed over the counter in Asia under various trade names (such as Brovarin), usually in combination with nonsteroidal anti-inflammatory drugs.

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Column 1Column 2
Skeletal formula of bromisoval
IUPAC name
(RS)-2-Bromo-N-carbamoyl-3-methylbutanamide
CAS Number.mw-parser-output .plainlist ol,.mw-parser-output .plainlist ul{line-height:inherit;list-style:none;margin:0;padding:0}.mw-parser-output .plainlist ol li,.mw-parser-output .plainlist ul li{margin-bottom:0}496-67-3 Y27109-49-5 R Y27109-48-4 S Y
3D model (JSmol)Interactive image
ChEBICHEBI:31304
ChEMBLChEMBL1515611 Y
ChemSpider2353 Y129594 R Y643139 S Y
ECHA InfoCard100.007.115
EC Number207-825-7
KEGGD01391
MeSHBromisovalum
PubChem CID2447146955 R735997 S
UNII469GW8R486 Y3DY4YGA2PX R YGTJ4Y0JW4D S Y
CompTox Dashboard (EPA)DTXSID2040656
InChI
InChI=1S/C6H11BrN2O2/c1-3(2)4(7)5(10)9-6(8)11/h3-4H,1-2H3,(H3,8,9,10,11) YKey: CMCCHHWTTBEZNM-UHFFFAOYSA-N Y
SMILES
CC(C)C(Br)C(=O)NC(N)=O
Chemical formulaC6H11BrN2O2
Molar mass223.070 g·mol−1
log P1.057
Acidity (pKa)10.536
Basicity (pKb)3.461
ATC codeN05CM03 (WHO)
Routes ofadministrationOral
Related ureasCarbromal
Related compounds3-Ureidopropionic acidbeta-Ureidoisobutyric acidCarbamoyl aspartic acidN-Acetylaspartic acidAceglutamideN-Acetylglutamic acidCitrulline
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Infobox references | |

Bromisoval (INN), commonly known as bromovalerylurea, is a hypnotic and sedative of the bromoureide group discovered by Knoll in 1907 and patented in 1909. It is marketed over the counter in Asia under various trade names (such as Brovarin), usually in combination with nonsteroidal anti-inflammatory drugs.

Chronic use of bromisoval has been associated with bromine poisoning.

Bromisoval can be prepared by bromination of isovaleric acid by the Hell-Volhard-Zelinsky reaction followed by reaction with urea.

  • Acecarbromal
  • Carbromal
  • Apronal

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