Beraunite

Iron phosphate mineral
title: "Beraunite" type: doc version: 1 created: 2026-02-28 author: "Wikipedia contributors" status: active scope: public tags: ["iron(ii,iii)-minerals", "phosphate-minerals", "hydroxide-minerals", "monoclinic-minerals", "tetrahydrate-minerals", "minerals-in-space-group-15"] description: "Iron phosphate mineral" topic_path: "general/iron-ii-iii-minerals" source: "https://en.wikipedia.org/wiki/Beraunite" license: "CC BY-SA 4.0" wikipedia_page_id: 0 wikipedia_revision_id: 0
::summary Iron phosphate mineral ::
::data[format=table title="infobox mineral"]
| Field | Value |
|---|---|
| name | Beraunite |
| category | Phosphate minerals |
| image | Beraunite-Kidwellite-214676.jpg |
| imagesize | 260px |
| caption | Crystalline beraunite on green kidwellite, Coon Creek Mine, Polk County, Arkansas, US. Size: 3.4 × 3.3 × 2.8 cm |
| formula | Fe2+ Fe3+5(OH)5(PO4)4·4H2O |
| IMAsymbol | Bru |
| strunz | 8.DC.27 |
| system | Monoclinic |
| class | Prismatic (2/m) |
| (same H-M symbol) | |
| symmetry | C2/c |
| unit cell | a = 20.953(8) Å, b = 5.171(1) Å, c = 19.266(4) Å; β = 93.34°; Z = 4 |
| color | Dull greenish to greenish brown when fresh, may be color banded; reddish brown to hyacinth-red, blood-red on exposure |
| habit | Tabular crystals common, may be in coarse radially fibrous aggregates, |
| twinning | On {100}, may be interpenetrant |
| cleavage | On {100}, good |
| mohs | 3–4 |
| luster | Vitreous, pearly on cleavages, resinous on fractures |
| streak | Olive-drab when fresh; yellow, brownish yellow on exposure |
| diaphaneity | Translucent |
| gravity | 2.8–3.08 (measured); 2.894 (calculated) |
| opticalprop | Biaxial (+) |
| refractive | nα = 1.775 nβ = 1.786 nγ = 1.815 |
| birefringence | δ = 0.040 |
| pleochroism | X = pale flesh-pink, yellow, blue-green; Y = pale flesh-pink, yellow, pale olive-green; Z = carnelian-red, reddish brown, olive-green. |
| 2V | Measured: 30° to 60°, Calculated: 66° |
| references | |
| :: |
| name = Beraunite | category = Phosphate minerals | image = Beraunite-Kidwellite-214676.jpg | imagesize = 260px | alt = | caption = Crystalline beraunite on green kidwellite, Coon Creek Mine, Polk County, Arkansas, US. Size: 3.4 × 3.3 × 2.8 cm | formula = Fe2+ Fe3+5(OH)5(PO4)4·4H2O | IMAsymbol=Bru | molweight = | strunz = 8.DC.27 | dana = | system = Monoclinic | class = Prismatic (2/m) (same H-M symbol) | symmetry = C2/c | unit cell = a = 20.953(8) Å, b = 5.171(1) Å, c = 19.266(4) Å; β = 93.34°; Z = 4 | color = Dull greenish to greenish brown when fresh, may be color banded; reddish brown to hyacinth-red, blood-red on exposure | colour = | habit = Tabular crystals common, may be in coarse radially fibrous aggregates, globular or discoidal, and in crusts | twinning = On {100}, may be interpenetrant | cleavage = On {100}, good | fracture = | tenacity = | mohs = 3–4 | luster = Vitreous, pearly on cleavages, resinous on fractures | streak = Olive-drab when fresh; yellow, brownish yellow on exposure | diaphaneity = Translucent | gravity = 2.8–3.08 (measured); 2.894 (calculated) | density = | polish = | opticalprop = Biaxial (+) | refractive = nα = 1.775 nβ = 1.786 nγ = 1.815 | birefringence = δ = 0.040 | pleochroism = X = pale flesh-pink, yellow, blue-green; Y = pale flesh-pink, yellow, pale olive-green; Z = carnelian-red, reddish brown, olive-green. | 2V = Measured: 30° to 60°, Calculated: 66° | dispersion = | extinction = | length fast/slow = | fluorescence= | absorption = | melt = | fusibility = | diagnostic = | solubility = | other = | alteration = | references =
Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primary phosphate minerals in granite pegmatites.
Beraunite crystallizes in the monoclinic crystal system with point group 2/m. Beraunite's formula is Fe2+ Fe3+5(OH)5(PO4)4·4H2O. Aluminium and zinc may substitute in the structure.
Occurrence
::figure[src="https://upload.wikimedia.org/wikipedia/commons/f/fd/Strengite-Beraunite-Hematite-67995.jpg" caption="Rosettes of colorless beraunite with lavender spheres of [[strengite]] on massive [[hematite]], Leveäniemi Mine, [[Svappavaara]], Sweden. Overall size 5.5 × 4.5 × 3.8 cm."] ::
Beraunite occurs as a secondary mineral in iron ore deposits and as an alteration product of primary phosphates minerals in granite pegmatites. It is found as an alteration product of triphylite at the Big Chief and Hesnard mines, Keystone, Pennington County, South Dakota, New Hampshire, in Arkansas, New Jersey and Pennsylvania in the United States. It is also found in Ireland, Germany, and the Czech Republic.
Structure
It occurs as fibrous greenish-black to brown nodules. The chemical analysis of beraunite often show small and irrational amounts of ferrous iron. The chain segments in Beraunite are one and two octahedral in length. Beraunite has two different types which are Zn-rich and Al-rich Beraunites, those two types have variations in data between those taken by Krsano in the X-ray powder diffraction experiment and those in the literature. Phosphate minerals have special characteristics about their chemical composition. The polyatomic complex of iron-oxygen octahedral face is sharing triplets corner to four other octahedral in the arrangement of atoms of the basic iron phosphates like dufrenite, rockbridgeite, and Beraunite. This complex is linked together by the phosphate tetrahedra.
References
References
- Warr, L.N.. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine.
- [http://rruff.geo.arizona.edu/doclib/hom/beraunite.pdf Handbook of Mineralogy]
- [http://www.mindat.org/min-628.html Mindat.org]
- [http://www.webmineral.com/data/Beraunite.shtml Webmineral data]
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